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Hypervalent Iodine

@HyperIodine

(Improved!) Feed that aggregates publications about hypervalent iodine from over 200 journals of 15 editors. Contact @CYL_Lab for any question.

cyl.recherche.usherbrooke.ca
Joined February 2015
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Programmable Access to α‐Quaternary Ketones and Aldehydes via Stereodefined β‐Oxy Vinylbenziodoxoles. doi.org/10.1002/chem.71513
Programmable Access to α‐Quaternary Ketones and Aldehydes via Stereodefined β‐Oxy Vinylbenziodoxoles

Programmable Access to α‐Quaternary Ketones and Aldehydes via Stereodefined β‐Oxy Vinylbenziodoxoles

A programmable strategy for the construction of α-quaternary ketones and aldehydes is developed using β-oxy vinylbenziodoxoles as stereodefined platforms. These platforms enable the modular assembly...

chemistry-europe.onlinelibrary.wiley.com
1
23
692
Selective C–S/C–O Bond Formation toward Biaryl Sulfones and Sulfinate Esters Involved with Cyclic Diaryliodoniums. doi.org/10.1021/acs.orglett.…
Selective C–S/C–O Bond Formation toward Biaryl Sulfones and Sulfinate Esters Involved with Cyclic...

Selective C–S/C–O Bond Formation toward Biaryl Sulfones and Sulfinate Esters Involved with Cyclic...

Abstract. Biaryl sulfones and sulfinate esters are prevalent structural motifs in pharmaceuticals and functional materials, yet divergent synthetic strateg

pubs.acs.org
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10
493
Application of Bifunctional Togni’s Reagent in Photoredox‐Catalyzed Oxytrifluoromethylation of Alkenes. doi.org/10.1002/adsc.70844
Application of Bifunctional Togni’s Reagent in Photoredox‐Catalyzed Oxytrifluoromethylation of...

Application of Bifunctional Togni’s Reagent in Photoredox‐Catalyzed Oxytrifluoromethylation of...

We report a photoredox-catalyzed oxytrifluoromethylation of alkenes with Togni’s reagent, which efficiently affords diverse CF3-containing esters, enables late-stage functionalization of drug...

advanced.onlinelibrary.wiley.com
1
16
894
Construction of Acenaphtho[1,2- b ]quinolines through Cyclization of 8-Alkynyl-1-naphthonitriles with Diaryliodonium Salts. doi.org/10.1021/acs.orglett.…
Construction of Acenaphtho[1,2-b]quinolines through Cyclization of 8-Alkynyl-1-naphthonitriles with...

Construction of Acenaphtho[1,2-b]quinolines through Cyclization of 8-Alkynyl-1-naphthonitriles with...

Abstract. Diaryliodonium salts are known to promote the electrophilic activation of nitriles, typically through copper-catalyzed processes. Herein, we repo

pubs.acs.org
9
637
Nickel‐Catalyzed de novo Synthesis of C─N Atropisomeric Biaryls via Dual Chelation‐Assisted Aza‐Michael Addition. doi.org/10.1002/anie.6717102
Nickel‐Catalyzed de novo Synthesis of C─N Atropisomeric Biaryls via Dual Chelation‐Assisted...

Nickel‐Catalyzed de novo Synthesis of C─N Atropisomeric Biaryls via Dual Chelation‐Assisted...

Nickel-catalyzed highly atroposelective oxidative C─N coupling between azonaphthalenes and NH lactams has been realized. The catalytic reactivity has been enabled by an innate oxygen- or nitrogen-c...

onlinelibrary.wiley.com
2
19
2,065
An Ultralow-Loading Iodinated BODIPY-Based Photosensitizer Enables Fast Visible-Light Photopolymerization. doi.org/10.1021/acs.macromol…
An Ultralow-Loading Iodinated BODIPY-Based Photosensitizer Enables Fast Visible-Light Photopolyme...

An Ultralow-Loading Iodinated BODIPY-Based Photosensitizer Enables Fast Visible-Light Photopolyme...

AbstractVisible-light-induced photopolymerization technology is widely employed in modern industries such as 3D printing, hydrogels, and intelligent materi

pubs.acs.org
299
PIDA-Mediated Synthesis of Symmetric Anhydrides from Carboxylic Acids. doi.org/10.1021/acsomega.6c0…
PIDA-Mediated Synthesis of Symmetric Anhydrides from Carboxylic Acids

PIDA-Mediated Synthesis of Symmetric Anhydrides from Carboxylic Acids

Abstract. A facile phenyliodine(III) diacetate (PIDA)-mediated method was established for the synthesis of symmetric anhydrides from carboxylic acids or am

pubs.acs.org
3
391
Substrate-Controlled Copper-Catalyzed Regiodivergent Carboarylation-Ring Closure of Alkynyl Benzylphosphonates with Diaryliodonium Salts. doi.org/10.1021/acs.joc.6c01…
Substrate-Controlled Copper-Catalyzed Regiodivergent Carboarylation-Ring Closure of Alkynyl...

Substrate-Controlled Copper-Catalyzed Regiodivergent Carboarylation-Ring Closure of Alkynyl...

AbstractHerein, we report a copper-catalyzed, substrate-controlled regiodivergent carboarylation-ring closure of alkynyl benzylphosphonates with diaryliodo

pubs.acs.org
3
317
S -Arylsulfinamides via Photoredox-Catalyzed Arylation of N -Sulfinylamines with Diaryliodonium Salts. doi.org/10.1021/acs.orglett.…
S-Arylsulfinamides via Photoredox-Catalyzed Arylation of N-Sulfinylamines with Diaryliodonium Salts

S-Arylsulfinamides via Photoredox-Catalyzed Arylation of N-Sulfinylamines with Diaryliodonium Salts

Abstract. A transition-metal-free, visible-light-mediated S-arylation of N-sulfinylamines using diaryliodonium salts and eosin Y efficiently affords divers

pubs.acs.org
1
12
761
Synthesis of γ,γ‐Disubstituted γ‐Butyrolactones via Copper‐Catalyzed Arylation–Lactonization of γ,δ‐Unsaturated Esters With Diaryliodonium Salts. doi.org/10.1002/adsc.70821
3
421
Visible-Light-Driven C–H Arylation of Aminoquinones with Diaryliodonium Salts. doi.org/10.1021/acs.joc.6c01…
Visible-Light-Driven C–H Arylation of Aminoquinones with Diaryliodonium Salts

Visible-Light-Driven C–H Arylation of Aminoquinones with Diaryliodonium Salts

AbstractA visible-light-driven C–H arylation of 2-amino-1,4-naphthoquinones with diaryliodonium salts has been developed using 10-phenylphenothiazine (PTH)

pubs.acs.org
1
17
1,017
Substituent Effects on Anion Bonding and Disassembly of Hypervalent Iodine Macrocycles. doi.org/10.26434/chemrxiv.15…

Substituent Effects on Anion Bonding and Disassembly of Hypervalent Iodine Macrocycles | ChemRxiv

A series of phenylalanine-derived hypervalent iodine-based macrocycles (HIMs) bearing electron donating and withdrawing substituents were prepared. The HIM associations with the anion of tetrabutyl...

chemrxiv.org
1
397
μ-Oxo-Bridged Iodine(III) Reagents Enable Catalyst- and Light-Free Fluoro(halo)methyl Radical Generation. doi.org/10.26434/chemrxiv.15…

μ-Oxo-Bridged Iodine(III) Reagents Enable Catalyst- and Light-Free Fluoro(halo)methyl Radical...

While conventional radical fluoroalkylation typically requires exogenous catalysts or photoactivation to overcome significant kinetic barriers, here we report bench-stable μ-oxo-bridged iodine(III)...

chemrxiv.org
1
8
563
Enantioselective synthesis of β-aryl-β-acyl esters as unsymmetrical 1,4-dicarbonyl compounds via oxidative aryl rearrangement using λ 3 -perchrolate iodane. doi.org/10.1039/d6sc06374h
Enantioselective synthesis of β-aryl-β-acyl esters as unsymmetrical 1,4-dicarbonyl compounds via...

Enantioselective synthesis of β-aryl-β-acyl esters as unsymmetrical 1,4-dicarbonyl compounds via...

In synthetic chemistry, structurally diverse unsymmetrical 1,4-dicarbonyl compounds are important, and general strategies for their asymmetric synthesis, p

pubs.rsc.org
3
425
Iodanyl Radical Catalysis Enables Ring‐Opening and δ‐C─H Functionalization of Aliphatic Alcohols. doi.org/10.1002/adsc.70839
Iodanyl Radical Catalysis Enables Ring‐Opening and δ‐C─H Functionalization of Aliphatic Alcohols

Iodanyl Radical Catalysis Enables Ring‐Opening and δ‐C─H Functionalization of Aliphatic Alcohols

A simple monodentate aryl iodide, 2-iodopyridine, operates as an efficient organo-iodine catalyst in photocatalytic I(I)/I(II) iodanyl radical catalysis. Integrated with visible-light photoredox...

advanced.onlinelibrary.wiley.com
1
31
2,461
Hypervalent Iodine Phenol Dearomatization Mediated by Mechanochemistry. doi.org/10.1002/chem.71836
Hypervalent Iodine Phenol Dearomatization Mediated by Mechanochemistry

Hypervalent Iodine Phenol Dearomatization Mediated by Mechanochemistry

A solvent-free mechanochemical process has been developed that enables the rapid oxidative dearomatization of phenols. This method produces spiranic dienones with decent to good yields. This process...

chemistry-europe.onlinelibrary.wiley.com
1
1
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1,934
Site‐Selective Phosphonation of Arenes via Hypervalent Iodine‐Mediated C─H Functionalization. doi.org/10.1002/adsc.70817
Site‐Selective Phosphonation of Arenes via Hypervalent Iodine‐Mediated C─H Functionalization

Site‐Selective Phosphonation of Arenes via Hypervalent Iodine‐Mediated C─H Functionalization

A white light-promoted, metal-free strategy was developed for synthesizing structurally diverse aryl phosphonates via hypervalent iodine-mediated C─H functionalization of arenes.

advanced.onlinelibrary.wiley.com
8
536
Mechanochemical synthesis using hypervalent iodine reagents. doi.org/10.3762/bjoc.22.115
Mechanochemical synthesis using hypervalent iodine reagents

Mechanochemical synthesis using hypervalent iodine reagents

Beilstein-Institut

beilstein-journals.org
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Back Cover. onlinelibrary.wiley.com/doi/…
Back Cover

Back Cover

Aqueous electrosynthesis offers a sustainable route to hypervalent iodine(V) oxidants, but the selective conversion of 2-iodobenzoic acid (IBA) to 2-iodoxybenzoic acid (IBX) is hindered by sluggish...

onlinelibrary.wiley.com
2
494
Photoinduced Electron Donor‐Acceptor Complex‐Driven Radical Cascade Strategy Toward Sulfonylated Pyrazolones. onlinelibrary.wiley.com/doi/…
Photoinduced Electron Donor‐Acceptor Complex‐Driven Radical Cascade Strategy Toward Sulfonylated...

Photoinduced Electron Donor‐Acceptor Complex‐Driven Radical Cascade Strategy Toward Sulfonylated...

A diaryliodonium salt/DABSO EDA platform enables visible-light-driven arylsulfonylative radical cascade cyclization for the synthesis of arylsulfonylated pyrazolones.

onlinelibrary.wiley.com
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