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It's all a bit empiricism vs rationalism. By only considering "optical experiments" and other direct measurements there is the potential for multiple explanations/guessing that can fit observation but doesn't equal truth of the matter.
With further points of reference and...
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So 2nd law doesn't exist independent of others. As a function of the conservation of internal energy, gasses/atmosphere have expansion limits. As the molecules expanding apart increases the potential energy between them the kinetic energy must decrease eventually slowing down...
